Adsorption of Metal Ions from Single and Binary Aqueous Systems on Bio-Nanocomposite, Alginate-Clay.

The aim of this work is to characterize and evaluate the retention of Cu2+ and Ni2+ from single and binary systems by alginate-Moroccan clay bio-composite with the utilization of calcium chloride as a cross-linking agent, using the ionotropic gelation method. The bio-nanocomposite was characterized by using a variety of techniques (SEM, EDX, XRD, and pHPZC). The efficiency of the adsorbent was investigated under different experimental conditions by varying parameters such as pH, initial concentration, and contact time. To demonstrate the adsorption kinetics, various kinetic models were tried and assessed, including pseudo-first-order, pseudo-second-order, intraparticle diffusion, and Elovich models. The research results show that the adsorption process of Cu2+ and Ni2+ metal ions follows a pseudo-second-order kinetic model, and the corresponding rate constants were identified. To evaluate the parameters related to the adsorption process in both single and binary systems, different mathematical models of isotherms, such as Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich, were investigated. The correlation coefficients obtained showed that the most suitable isotherm for describing this adsorption process is the Langmuir model. The process is considered to be physical and endothermic, as suggested by the positive values of ΔH° and ΔS°, indicating increased randomness at the solid/liquid interface during Cu2+ and Ni2+ adsorption. Furthermore, the spontaneity of the process is confirmed by the negative values of ∆G°. The bio-nanocomposite beads demonstrated a maximum adsorption capacity of 370.37 mg/g for Ni2+ and 454.54 mg/g for Cu2+ in the single system. In the binary system, the maximum adsorption capacities were observed to be 357.14 mg/g for Ni2+ and 370.37 mg/g for Cu2+. There is significant evidence for the use of alginate-Moroccan clay bio-nanocomposite as a cost-effective alternative adsorbent for the efficient removal of metal ions in single and binary systems.

Novel insights into crystal violet dye adsorption onto various macroalgae: Comparative study, recyclability and overview of chromium (VI) removal.

In this study, effective biomaterials were prepared from marine macroalgae, namely Fucus spiralis (F.S), Ulva intestinalis (U.I), and Corallina officinalis (C.O). The ability to adsorb the hazardous organic dye crystal violet (CV) was examined, revealing different adsorptive properties for the three algae. The removal of CV dye occurred onto only a homogeneous monolayer for F.S, and both a homogeneous monolayer and a heterogeneous multilayer for U.I and C.O algae. The predicted monolayer capacities at 25 °C were approximately 53 mg/g, 55 mg/g, and 97 mg/g for F.S, C.O, and U.I, respectively. The adsorption of CV dye on all the algae was found to follow a pseudo-second-order rate. Ulva intestinalis algae, as a potential adsorbent of CV dye, were also tested in the adsorption of inorganic substances and demonstrated significant efficiency in the removal of chromium (VI). The findings highlight various adsorption properties and the relevance of macroalgae for wastewater treatment applications.

Alginate-Moroccan Clay, New Bio-Nanocomposite for Removal of H2PO4-, HPO42-, and NO3- Ions from Aqueous Solutions.

The aim of this work is to synthesize and characterize alginate-Moroccan clay bio-composite in order to improve our understanding of the adsorption of inorganic pollutants found in textile effluents. Characterization of the bio-composite used was carried out using a variety of techniques (IR-TF, SEM, DRX, and pHZPC). The influence of the medium's physico-chemical parameters (temperature, pH, initial concentration, etc.) on the retention of inorganic pollutants was also studied. Studies of adsorption and inorganic pollutants such as orthophosphate (H2PO4- and HPO42-) and nitrate (NO3-) ions were carried out, using simple solutions from the laboratory, in a batch system. This study explored the impact of adsorbent dose, contact time, solution pH, and temperature on the adsorption process. Various kinetic models, including pseudo-first-order, pseudo-second-order, intra-particle diffusion, and Elovich models, were tested and evaluated, to illustrate the adsorption kinetics. This study's findings demonstrated that the adsorption process follows second-order kinetics, with associated rate constants successfully determined. The correlation coefficient for the pseudo-second-order kinetic model is nearly equal to 1 (>0.98), and the value of theoretical adsorption capacity (qe,the) is comparable to the experimental one (qe,the = 58.14 mg/g for H2PO4-, qe,the = 54.64 mg/g for HPO42-, and qe,the = 52.63 mg/g for NO3-). Additionally, the adsorption equilibrium was investigated through the application of various mathematical models, including the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherm models, to assess the mechanistic parameters associated with the adsorption process. Among these models, the Langmuir isotherm emerged as the most suitable one for characterizing the adsorption of H2PO4-, HPO42-, and NO3- ions using bio-nanocomposite beads. The maximum adsorbed amounts of metal ions by the bio-nanocomposite used were 625 mg/g for H2PO4-, 909.09 mg/g for HPO42-, and 588.23 mg/g for NO3- from the batch system. The endothermic and physical nature of the adsorption is suggested by the positive values of ΔH°, which is consistent with experimental findings. The adsorption process is spontaneous, as evidenced by the negative ΔG° values. Positive ΔS° values indicate increased randomness at the solid/liquid interface during adsorption of ion-organic ions onto the engineered bio-nanocomposite. The obtained results demonstrated that, from a scientific perspective, alginate-Moroccan clay bio-nanocomposites exhibit a highly significant adsorption capability for the removal of oxyanions in aqueous environments.

Efficient removal of Cr (VI) from aqueous solution using memory effect property of layered double hydroxide material.

Treating wastewater containing pollutants with layered double hydroxide (LDH) material attracts excellent interest. LDH materials are known by the memory effect property, which leads to the reconstruction of the LDH structure after its calcination and rehydration. In this study, LDH material was prepared, calcined, and then rehydrated in an aqueous Cr(VI) solution. XRD, FTIR, and SEM-EDS analysis confirm the successful reconstruction of LDH-loading chromium on its surface and layered space. Response surface methodology (RSM) results showed that LDH mass, contact time, and chromium concentration are the main factors controlling the removal of Cr(VI). The heterogeneous sorption of chromium was described by fitting the equilibrium data to the Freundlich model. Analytical techniques, thermodynamic data, activation, and adsorption energies confirm that the removal process of Cr(VI) is endothermic, spontaneous, and physical nature. LDH exhibits good reusability performance with only a 7% reduction of initial adsorption capacity after five cycles of the calcination-rehydration process. These results show that the memory effect of LDH is helpful for the intercalation and the removal of emergent pollutants, especially for wastewater treatment.

An efficient and adsorption of methylene blue dye on a natural clay surface: modeling and equilibrium studies.

The present research work revolves around the evaluation of the elimination of the cationic dye methylene blue (MB) from an aqueous solution by the exploitation of natural clay (TMG) from South-East Morocco. Several physicochemical techniques were used to characterize our TMG adsorbate, namely, X-ray diffraction, Fourier transform infrared absorption spectroscopy, differential thermal analysis, thermal gravimetric analysis, and zero charge point (pHpzc). The morphological properties and elemental composition of our material were identified using scanning electron microscopy coupled with an energy-dispersive X-ray spectrometer. The batch technique was used under different operating conditions to produce quantitative adsorption, namely, the amount of adsorbent, dye concentration, contact time, pH, and solution temperature. The maximum adsorption capacity of MB on TMG was 81.185 mg g-1 for a concentration of 100 mg L-1 MB at pHinitial = 6.43 (no initial adjustment of the pH-value was performed), temperature 293 K, and 1 g L-1 adsorbent. The adsorption data were examined by Langmuir, Freundlich, and Temkin isotherms. The Langmuir isotherm provides the best correlation with the experimental data, and the pseudo-second-order kinetic model is more appropriate for the adsorption of the MB dye. The thermodynamic study of MB adsorption indicates that the process is physical, endothermic, and spontaneous. The Box-Behnken method was applied to identify the optimal conditions for MB removal in the design of batch experiments. The parameters examined result in >99% removal. The TMG material's regeneration cycles and low cost ($0.393 per gram) show that it is both environmentally friendly and very effective for dye removal in the various textile sectors.

Synthesis, characterization, and comparative study of MgAl-LDHs prepared by standard coprecipitation and urea hydrolysis methods for phosphate removal.

Layered double hydroxides (LDHs), known as a class of anionic clays, have attracted considerable attention recently due to their potential applications in different areas as catalyst materials, energy materials, and adsorbent materials for environmental remediation, especially for anionic pollutant removal. In this study, magnesium aluminum layered double hydroxide (MgAl-LDH) was synthesized by two methods: standard coprecipitation and urea hydrolysis. Their textural properties and morphologies were examined by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), thermogravimetry (TG) and differential (DTG) analysis, and point of zero charge (pHpzc). The specific surface area was calculated from BET adsorption equation. The results indicated that the crystallinity and the regularity of the samples prepared by urea hydrolysis were much preferable to those prepared by the coprecipitation method. Their sorption properties toward phosphate were investigated and the experimental evidence showed that, at the initial concentration of 100 mg L-1 and at room temperature, the LDH synthesized by urea hydrolysis had a percentage removal of 94.3 ± 1.12% toward phosphate ions while 74.1 ± 1.34% were uptaked by LDH synthesized by coprecipitation method, suggesting that the crystallinity affects the sorption capability. The sorption mechanism indicates that phosphate ions could be sorbed onto LDHs via electrostatic attraction, ligand exchange, and ion exchange.

Wastewater treatment by batch adsorption method onto micro-particles of dried Withania frutescens plant as a new adsorbent.

A new adsorbent for removing metallic elements, nitrate and phosphate ions from municipal and industrial wastewaters has been investigated. This new adsorbent consists of micro-particles of dried Withania frutescens plant (<500 µm). Batch experiments were conducted to evaluate the removal of metallic elements and anions from raw wastewaters by W. frutescens particles. The results show that the micro-particles of W. frutescens plant presented a good adsorption of metallic elements, nitrate and phosphate ions from both real wastewaters. This adsorption increased with increasing of contact time. The percentage of metallic elements removal from industrial wastewater by W. frutescens plant was 98 ≈ 99% for Pb(II), 92 ≈ 93% for Cd(II), 91 ≈ 92% for Cu(II) and 92 ≈ 93% for Zn(II). The maximum adsorption capacity was dependent on the type of ions. The results also indicate that the values of chemical oxygen demand (COD) decrease after the contact with W. frutescens particles. Based on the results it can be concluded that the dried W. frutescens plant appears to be an economical and environmentally friendly material for wastewater treatment.

Single, binary and multi-component adsorption of some anions and heavy metals on environmentally friendly Carpobrotus edulis plant.

A low-cost adsorbent and environmentally friendly adsorbent from Carpobrotus edulis plant was used for the removal of NO(3)(-), H(2)PO(4)(-), Pb(2+) and Cd(2+) ions from single, binary and multi-component systems. The efficiency of the adsorbent was studied using batch adsorption technique under different experimental conditions by varying parameters such as pH, initial concentration and contact time. In single component systems, the dried C. edulis has the highest affinity for Pb(2+), followed by NO(3)(-), Cd(2+) and H(2)PO(4)(-), with adsorption capacities of 175mg/g, 125mg/g, 28mg/g and 26mg/g, respectively. These results showed that the adsorption of NO(3)(-) and H(2)PO(4)(-) ions from single and binary component systems can be successfully described by Langmuir and Freundlich isotherms. Freundlich adsorption model, showed the best fit to the single and binary experimental adsorption data. These results also indicated that the adsorption yield of Pb(2+) ion was reduced by the presence of Cd(2+) ion in binary metal mixture. The competitive adsorption of NO(3)(-), H(2)PO(4)(-), Pb(2+) and Cd(2+) ions on dried C. edulis plant shows that NO(3)(-) and H(2)PO(4)(-) anions are able to adsorb on different free binding sites and Pb(2+) and Cd(2+) cations are able to adsorb on the same active sites of C. edulis particles. The dried C. edulis was found to be efficient in removing nitrate, phosphate, cadmium and lead from aqueous solution as compared to other adsorbents already used for the removal of these ions.